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Hello Faz :)
As I understand it, if you are signed in with a MS account you will not be able to remove it. What you can do is convert you account back to a local account. See https://www.tenforums.com/tutorials/5...dows-10-a.html
To delete a user account in Windows 10, see this tutorial: User Account - Delete in Windows 10 - Windows 10 Forums
However, your screenshot hints that instead of removing a Windows user account, you'd like to remove one of the additional accounts used by yourself, an account seen on your account page under Email, calendar and contacts or Accounts used by other apps.
These your additional accounts are not Windows user accounts and can easily be removed by selecting an account and clicking Manage:
In the following dialog select Delete account:
Finally click Delete:
Kari
Hey Phil,
It Was Very Helpful...Thank U For A Quick Reply