Tried To Change New Content Storage Loction And Now Have Folder Issues

That's a safe way. Provided you're the only user and don't need folders under user profiles, it should be fine. A few people have got themselves into quite some difficulty making mistakes relocating folders.

You might want to call your folders a unique name e.g.
My Documents vs Documents
My Downloads vs Downloads

- so you can easily distinguish them.

It's also helpful to assign icons to folders so they stand out.

Here you can see some of the default library folders and a couple of mine on H: in Quick Access