The details were taken from Speccy, and are part of the section related to the motherboard, I have now attached a notepad file of the whole screen.
My computer is not the youngest and problems arose recently, but are now solved, but the stats here seemed a little strange, so I wanted to know if what I saw was a warning sign.
The only thing I see wrong is the +12V. However, I am reasonably sure it is just a false reading. At that voltage the computer wouldn't run at all. So, it seems you just have an incorrect meeting or a faulty sensor on the motherboard. Neither one has anything to do with how your computer runs.
Your PC wouldn't run as others have said if your voltages were that far out. It seems you may have a problem with the motherboard sensors or software. You could try different monitoring software. I use CPU ID Hardware Monitor http://www.cpuid.com/softwares/hwmonitor.html