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#11
In Disk Management, right click in the Disk number box, click Properties, click Volumes tab and note what it says. If the Partition style says "GUID Partition Table (GPT) then you are using UEFI and you should be able to simply right click that unallocated box and create a usable partition. If it says MBR then as stated, you've run into the 2.2TB limit and will have to set the BIOS to UEFI and either reinstall Windows (the easy way) making sure you've backed up your data, or go with option two as posted by Megahertz.
Please post the image for us to see. Also what actually happens when you right click inside that unallocated box. Is there an option to create a "New Simple Volume"?